Saturday, 21 November 2015

Little bit Introduction About MHD Generation

INTRODUCTION

     Magneto hydrodynamics (MHD) (magneto fluid dynamics or hydro magnetics) is the academic discipline which studies the dynamics of electrically conducting fluids. Examples of such fluids include plasmas, liquid metals, and salt water. The word magneto hydro dynamics (MHD) is derived from magneto- meaning magnetic field, and hydro- meaning liquid, and -dynamics meaning movement. The field of MHD was initiated by Hannes Alfvén , for which he received the Nobel Prize in Physics in 1970

o  80 % of total electricity produced in the world is hydal, while remaining 20% is produced from nuclear, thermal, solar, geothermal energy and from magneto hydro dynamic (mhd) generator.
o  MHD power generation is a new system of electric power generation which is said to be of high efficiency and low pollution. In advanced countries MHD generators are widely used but in developing countries like INDIA, it is still under construction, this construction work in in progress at TRICHI in TAMIL NADU, under the joint efforts of BARC (Bhabha atomic research center), Associated cement corporation (ACC) and Russian technologists.
o  As its name implies, magneto hydro dynamics (MHD) is concerned with the flow of a conducting fluid in the presence of magnetic and electric field. The  fluid may be gas  at elevated temperatures or liquid metals like sodium or potassium- SEEDING.

o  An MHD generator is a device for converting heat energy of a fuel directly into electrical energy without conventional electric generator.
o  In this system. An MHD converter system is a heat engine in which heat taken up at a higher temperature is partly converted into useful work and the remainder is rejected at a temperature. Like all heat engines, the thermal efficiency of an MHD converter is increased by supplying the heat at the highest practical temperature and rejecting it at the lowest practical temperature.
o  The output of the MHD is supplied to the conventional Thermal Plants.

PRINCIPLES OF MHD POWER GENERATION


o  When an electric conductor moves across a magnetic field, a voltage is induced in it which produces an electric current.
o  This is the principle of the conventional generator where the conductors consist of copper strips.
o  In MHD generator, the solid conductors are replaced by a gaseous conductor, an ionized gas. If such a gas is passed at a high velocity through a powerful magnetic field, a current is generated and can be extracted by placing electrodes in suitable position in the stream.
o  The principle can be explained as follows. An electric conductor moving through a magnetic field experiences a retarding force as well as an induced electric field and current.
       This effect is a result of FARADAYS LAWS OF ELECTRO MAGNETIC INDUCTION.
o  The induced EMF is given by
Eind = u x B
where   u = velocity of the conductor.
 B = magnetic field intensity.
o  The induced current is given by,
 Jind = C x Eind
where C = electric conductivity
The retarding force on the conductor is the Lorentz force given by                                                                                   Find = Jind X B

The electro magnetic induction principle is not limited to solid conductors. The movement of a conducting fluid through a magnetic field can also generate electrical energy.

When a fluid is used for the energy conversion technique, it is called MAGNETO HYDRO DYNAMIC (MHD), energy conversion.

The flow direction is right angles to the magnetic fields
                direction. An electromotive force (or electric voltage) is induced in the direction at right angles to both flow and field directions, as shown in the next slide.
The conducting flow fluid is forced between the plates with a kinetic energy and pressure differential sufficient to over come the magnetic induction force Find.

The end view drawing illustrates the construction of the flow channel.

An ionized gas is employed as the conducting fluid.

Ionization is produced either by thermal means I.e. by an elevated temperature or by seeding with substance like cesium or potassium vapors which ionizes at relatively low temperatures.

The atoms of seed element split off electrons. The presence of the negatively charged electrons makes the gas an electrical conductor.


VARIOUS MHD SYSTEMS

The MHD systems are broadly classified into two types.

OPEN CYCLE SYSTEM
CLOSED CYCLE SYSTEM
                Seeded inert gas system
                Liquid metal system

OPEN CYCLE SYSTEM
The fuel used maybe oil through  an oil tank or gasified coal through a coal gasification plant

The fuel (coal, oil or natural gas) is burnt in the combustor or combustion chamber.

The hot gases from combustor is then seeded with a small amount of ionized alkali metal (cesium or potassium) to increase the electrical conductivity of the gas.

The seed material, generally potassium carbonate is injected into the combustion chamber, the potassium is then ionized by the hot combustion gases at temperature of roughly 2300’ c to 2700’c.

To attain such high temperatures, the compressed air is used to burn the coal in the combustion chamber, must be adequate to at least 1100’c. A lower preheat temperature would be adequate if the air is enriched in oxygen. An alternative is used to compress oxygen alone for combustion of fuel, little or no preheating is then required. The additional cost of oxygen might be balanced by saving on the preheater.
The hot pressurized working fluid living in the combustor flows through a convergent divergent nozzle. In passing through the nozzle, the random motion energy of the molecules in the hot gas is largely converted into directed, mass of energy. Thus , the gas emerges from the nozzle and enters the MHD generator unit at a high velocity.

The MHD generator is a divergent channel made of a heat resistant alloy with external water cooling. The hot gas expands through the rocket like generator surrounded by powerful magnet. During motion of the gas the +ve and –ve ions move to the electrodes and constitute an electric current.

The arrangement of the electrode connection is determined by the need to reduce the losses arising from the Hall effect. By this effect, the magnetic field acts on the MHD-generated current and produces a voltage in flow direction of the working fluid.

CLOSED CYCLE SYSTEM

Two general types of closed cycle MHD generators are being investigated.

Electrical conductivity is maintained in the working fluid by ionization of a seeded material, as in open cycle system.

A liquid metal provides the conductivity.

The carrier is usually a chemical inert gas, all through a liquid carrier is been used with a liquid metal conductor. The working fluid is circulated in a closed loop and is heated by the combustion gases using a heat exchanger. Hence the heat sources and the working fluid are independent. The working fluid is helium or argon with cesium seeding.

SEEDED INERT GAS SYSTEM

In a closed cycle system the carrier gas operates in the form of Brayton cycle. In a closed cycle system the gas is compressed and heat is supplied by the source, at essentially constant pressure, the compressed gas then expands in the MHD generator, and its pressure and temperature fall. After leaving this generator heat is removed from the gas by a cooler, this is the heat rejection stage of the cycle. Finally the gas is recompressed and returned for reheating.

The complete system has three distinct but interlocking loops. On the left is the external heating loop. Coal is gasified and the gas is burnt in the combustor to provide heat. In the primary heat exchanger, this heat is transferred to a carrier gas argon or helium of the MHD cycle. The combustion products after passing through the air preheated and purifier are discharged to atmosphere.

Because the combustion system is separate from the working fluid, so also are  the ash and flue gases. Hence the problem of extracting the seed material from fly ash does not arise. The fuel gases are used to preheat the incoming combustion air and  then treated for fly ash and sulfur dioxide removal, if necessary prior to discharge through a stack to the atmosphere.

The loop in the center is the MHD loop. The hot argon gas is seeding with cesium and resulting working fluid is passed through the MHD generator at high speed. The dc power out of MHD generator is converted in ac by the inverter and is then fed to the grid.

LIQUID METAL SYSTEM

When a liquid metal provides the electrical conductivity, it is called a liquid metal MHD system.
An inert gas is a convenient carrier

The carrier gas is pressurized and heated by passage through a heat exchanger within combustion chamber. The hot gas is then incorporated into the liquid metal usually hot sodium to form the working fluid. The latter then consists of gas bubbles uniformly dispersed in an approximately equal volume of liquid sodium.

The working fluid is introduced into the MHD generator through a nozzle in the usual ways. The carrier gas then provides the required high direct velocity of the electrical conductor.

After passage through the generator, the liquid metal is separated from the carrier gas. Part of the heat exchanger to produce steam for operating a turbine generator. Finally the carrier gas is cooled, compressed and returned to the combustion chamber for reheating and mixing with the recovered liquid metal. The working fluid temperature is usually around 800’c as the boiling point of sodium even under moderate pressure is below 900’c.

At lower operating temp, the other MHD conversion systems may be  advantageous from the material standpoint, but the maximum thermal efficiency is lower. A possible compromise might be to use liquid lithium, with a boiling point near 1300’c as the electrical conductor lithium is much more expensive than sodium, but losses in a closed system are less.

ADVANTAGES

The conversion efficiency of a MHD system can be around 50% much higher compared to the most efficient steam plants. Still higher efficiencies are expected in future, around 60 – 65 %, with the improvements in experience and technology.

Large amount of power is generated.

It has no moving parts, so more reliable.

The closed cycle system produces power, free of pollution.

It has ability to reach the full power level as soon as started.

The size if the plant is considerably smaller than conventional fossil fuel plants.

Although the cost cannot be predicted very accurately, yet it has been reported that capital costs of MHD plants will be competitive to conventional steam plants.

It has been estimated that the overall operational costs in a plant would be about 20% less than conventional steam plants.

Direct conversion of heat into electricity permits to eliminate the turbine (compared with a gas turbine power plant) or both the boiler and the turbine (compared with a steam power plant) elimination reduces losses of energy.

These systems permit better fuel utilization. The reduced fuel consumption would offer additional economic and special benefits and would also lead to conservation of energy resources.

It is possible to use MHD for peak power generations and emergency service. It has been estimated that MHD equipment for such duties is simpler, has capability of generating in large units and has the ability to make rapid start to full load.

FUTURE PROSPECTS

It  is estimated that by 2020, almost 70 % of the total electricity generated in the world will be from MHD generators.
Research and development is widely being done on MHD by different countries of the world.
Nations involved:
USA
Former USSR
Japan
India
China
Yugoslavia
Australia
Italy

Poland


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Sunday, 8 November 2015

Little bit of Introduction about Solar cell...

Every metal has its own band gap that describes how strong the electrons are bonded to the atoms. For semiconductors, such as silicon, the band gap refers to the energy difference between the valence band and the conduction band. When a negative electron is excited, it leaves behind a void which is called a positive hole. The presence of a missing covalent bond allows the bonded electrons of neighbouring atoms to jump into the hole, leaving another hole behind. Because of this, holes also move through the lattice. When photons are absorbed in the semiconductor, it can be said they create mobile electron-hole pairs.


The History Highlight of Solar Sells (Photovoltaic Cells)

1839 – The photovoltaic effect was discovered by Alexandre-Edmond Becquerel, who was a French physicist. This was “the beginning” of the solar cell technology. Becquerel's experiment was done by illuminating two electrodes with different types of light. The electrodes were coated by light sensitive materials, AgCl or AgBr, and carried out in a black box surrounded by an acid solution. The electricity increased when the light intensity increased.

1873 – The photo conductivity of an element, selenium, was discovered by Willoughby Smith, who was an English electrical engineer.

1876 – Selenium produces electrical current when it is exposed to sun light. William Grylls Adams and Richard Evans Day proved that it is possible to convert solar energy into electricity directly, without any moving parts or heat. The solar cell was very inefficient, and it couldn't be used to run any electrical equipment.

1883 – A description of the first solar cells made from selenium wafer were made by Charles Fritts.

1894 – Charles Fritts constructed what was probably the first true solar cell. He coated a semiconductor material (selenium) with an extremely thin layer of gold. The efficiency were only about 1%, so it couldn't be used as energy supply, but were later used as light sensors.

1904 – A German physicist, Wilhelm Ludwig Franz Hallwachs, discovered that a combination of copper and cuprous oxide was photosensitive.

1905 – Albert Einstein published his paper about the photoelectric effect. There he claimed that light consists of “packets” or quanta of energy, which we now call photons. This energy varies only with its frequency (electromagnetic waves, or the “color of the light”). This theory was very simple, but revolutionary, and it explained very well the absorption of the photons regarding to the frequency of the light.

1914 – Goldman and Brodsky noted that it existed a barrier layer in photovoltaic devices.

1916 – Robert Andrews Millikan provided experimental proof of the photoelectric effect. He was an American experimental physicist who later won the Nobel Prize for his work on the photoelectric effect and for his measurement of the charge of the electron.

1918 – Jan Czochralski, a Polish chemist, developed a way to grow single-crystal silicon. This increased the efficiency of the silicon-based cells considerably.

1923 – Albert Einstein received the Nobel Prize for his theories explaining the photoelectric effect, which he published 18 years earlier.

1930s – Walter Schottky, Neville Mott and some others developed a theory of metal-semiconductor barrier layers.

1932 – Audobert and Stora discover the photovoltaic effect in cadmium sulfide (CdS).

1950s – Bell Labs produce solar cells for space activities.

1951 – A grown p-n junction enabled the production of a single-crystal cell of germanium.

1953 – Dr. Dan Trivich of Wayne State University makes the first theoretical calculations of the efficiencies of various materials of different band-gap widths based on the spectrum of the sun

1954 – Three researchers, Gerald Pearson, Daryl Chapin and Calvin Fuller, at Bell Laboratories discovered a silicon solar cell, which was the first material to directly convert enough sunlight into electricity to run electrical devices. The efficiency of the silicon solar cell, which Bell Labs produced, were 4%, which later increased to 11%. The cells were made by hand and cost $1000 per watt.

1954 – A cadmium sulphide p-n junction was produced with an efficiency of 6%

1958 – Hoffman Electronics achieved 9% efficient PV cells.

1958 – The first PV-powered satellite, Vanguard I, was launched. The solar panel had an area of 100cm² and delivered an effect of approximately 0.1W. The satellite power system operated for 8 years, and is the world's oldest satellite still in orbit (2007).

1958 – Ted Mandelkorn of U.S. Signal Corps Laboratories fabricates n-on-p (negative layer on positive layer) silicon photovoltaic cells,

1959 – Hoffman Electronics achieved 10% efficient commercially available PV cells and demonstrated the use of a grid contact to significantly reduce series resistance.

1959 – Explorer-6 was launched with a PV array of 9600 cells, each only 1 cm x 2 cm.

1960 – Hoffman Electronics achieved 14% efficient PV cells.

1962 – The Telstar communications satellite, launched by Bell Labs, is initial powered (14W) by solar cells.

1963 – A Japanese electronics manufacturer, Sharp Corporation, produces a viable photovoltaic module of silicon solar cells.

1970 – First highly effective GaAs heterostructure solar cells are created by Zhores Alferov (a Russian physicist) and his team in the USSR.

1972 – The Institute of Energy Conversion is established at the University of Delaware to perform research and development on thin-film photovoltaic and solar thermal systems, becoming the world’s first laboratory dedicated to photovoltaic research and development.

1976 – David Carlson and Christopher Wronski of RCA Laboratories produced the first amorphous silicon photovoltaic cells, which could be less expensive to manufacture than crystalline silicon devices. The efficiency was of 1.1%.

1980 – At the University of Delaware, the first thin-film solar cell exceeds 10% efficiency. It's made of copper sulfide (Cu2S) and cadmium sulfide (CdS).

1981 – Paul MacCready builds the first solar-powered aircraft, the Solar Challenger, and flies it from France to England across the English Channel. The aircraft had over 16,000 solar cells mounted on its wings, which produced a power of 3kW.

1982 – Hans Tholstrup, an Australian, drives the first solar-powered car, the Quiet Achiever, 4,000km between Sydney and Perth in 20 days. That was 10 days faster than the first gasoline-powered car to do so. The maximum speed was 72 km/h, and the average speed was 24 km/h.

1984 – The IEEE Morris N. Liebmann Memorial Award was presented to Drs. David E. Carlson and Christopher R. Wronski at the 17th Photovoltaic Specialists Conference, "for crucial contributions to the use of amorphous silicon in low-cost, high-performance photovoltaic solar cells."

1985 – The University of South Wales breaks the 20% efficiency barrier for silicon solar cells under one sun conditions.

1989 – Reflective solar concentrators are first used with solar cells.

1991 – Efficient Photo electrochemical cells (PEC) are developed. Each cell consists of a semiconducting photo anode and a metal cathode immersed in an electrolyte. The Dye-sensitized solar cell (DSC), also called Grätzel cells, is invented. It was a new class of low-class DSC.

1992 – University of South Florida develops a 15.9% efficient thin-film photovoltaic cell made of cadmium telluride, breaking the 15% barrier for the first time for this technology.

1994 – The National Renewable Energy Laboratory develops a solar cell, made from gallium indium phosphide and gallium arsenide that becomes the first one to exceed 30% conversion efficiency.

1996 – Renewable Energy Corporation (REC), a Norwegian solar energy company established.

1996 – EPFL, the Swiss Federal Institute of Technology in Lausanne, achieves 11% efficiency with the DSCs.

1999 – Spectrolab, Inc. and the National Renewable Energy Laboratory develop a photovoltaic solar cell that converts 32.3 percent of the sunlight that hits it into electricity. The high conversion efficiency was achieved by combining three layers of photovoltaic materials into a single solar cell. The cell performed most efficiently when it received sunlight concentrated to 50 times normal. To use such cells in practical applications, the cell is mounted in a device that uses lenses or mirrors to concentrate sunlight onto the cell. Such “concentrator” systems are mounted on tracking systems that keep them pointed toward the sun.

1999 – The National Renewable Energy Laboratory achieves a new efficiency record for thin-film photovoltaic solar cells. The new measurement is of 18.8 percent efficiency.

2000 – Two new thin-film solar modules, developed by BP Solarex, break previous performance records. The company’s 0.5-square-meter module achieves 10.8 % conversion efficiency—the highest in the world for thin-film modules of its kind. And its 0.9-square-meter module achieved 10.6% conversion efficiency and a power output of 91.5 watts — the highest power output for any thin-film module in the world.

2001 – TerraSun LLC developes a method of using holographic films to concentrate sunlight onto a solar cell

2003 – REC Solar started production.

2007 – The University of Delaware achieves a 42.8% efficiency solar cell technology.


The photovoltaic effect
Photovoltaic is a term in solar technology that describe a solar cells ability to convert light from the sun directly into electric power. When photons in the sun light collide with the silicon solar cell, one of three things can happen:
  • The photon can be reflected at the surface of the silicon
  • The photon can be absorbed by the silicon
  • The photon can pass right through the silicon
As the photons hits the atoms in the silicon, the energy is absorbed by the electrons and excited into a higher state of energy. When these free electrons flow through the material, electricity arises.

Notice this is the case for semiconductors in general. Silicon does not have three valence and conduction bands.


The holes move to the negative layer of the cell, and the negative excited electrons move to the positive layer. This will be described by the p-n junction technique later. When placing a circuit between the two layers, a path of continuous flow of electrons is established.
Due to the concept conservation of energy, the excited electrons cannot have greater nor less energy than that of the incident rays from the sun. Photons with less energy than the energy gap will go straight through the semiconductor and no electrons will be excited. Photons with greater energy than the energy gap will be absorbed, but the difference in energy between the photons and the energy gap is converted into heat by lattice vibration.


HOW SOLAR CELLS WORK

A solar cell, sometimes called a photovoltaic cell, is a device that converts light energy into electrical energy. A single solar cell creates a very small amount of energy (about .6 volts DC) so they are usually grouped together in an integrated electrical panel called a solar panel. Sunlight is a somewhat diffuse form of energy and only a portion of the light captured by a solar cell is converted into electricity.  The current generation of solar cells converts only 12 to 15 per cent of the sun's light into electricity.  However in recent years there have been significant advances in their design.  Some new cells on the market now are around 20% efficient and some laboratory prototypes are reaching as high as  30 per cent.  Given this it is likely that their efficiency will continue to improve over time.

Theory Behind Solar Cells

A solar cell is based upon the "photovoltaic effect" discovered in 1839 by Edmund Becquerel, a French physicist.  In his experiments he found that certain materials would produce small amounts of electric current when exposed to sunlight.  Sunlight is made up of packets of energy called photons.  When the photons strike the semi-conductor layer (usually silicon) of a solar cell a portion of the photons are absorbed by the material rather than bouncing off of it or going through the material.  When a photon is absorbed the energy of that photon is transferred to an electron in an atom of the cell causing the electron to escape from its normal position.  This creates, in essence, a hole in the atom.  This hole will attract another electron from a nearby atom now creating yet another whole, which in turn is again filled by an electron from another atom.  This hole filling process is repeated a few zillion times and voila, an electric current is formed.

Structure of a Solar Cell

A typical solar cell is a multi-layered material. Let's review what the layers are:

Cover Glass - this is a clear glass layer that provides outer protection from the elements.
Transparent Adhesive - this holds the glass to the rest of the solar cell.
Anti-reflective Coating - this substance is designed to prevent the light that strikes the cell from bouncing off so that the maximum energy is absorbed into the cell.
Front Contact - transmits the electric current.
N-Type Semiconductor Layer - This is a thin layer of silicon which has been doped with phosphorous.
P-Type Semiconductor Layer - This is a thin layer of silicon which has been doped with boron.
Back Contact - transmits the electric current.

Types of Solar Cells

Because of the extensive research being done on solar energy there are now many types of solar cells on the market.  All of them follow the principles described when it comes to generating an electric current.  However, many different approaches are now used to create the structures in order to reduce the costs of production. These approaches involve a tradeoff between lower manufacturing costs versus lower efficiency in converting sunlight to electricity.  The three most common approaches are summarized below: 

Monocrystalline Silicon - This type of solar cell uses a single layer of silicon for the semi-conductor. In order to produce this type of silicon it must be extremely pure which means it is the most expensive type of solar cell to produce.

Polycrystalline Silicon - To make polycrystalline silicon cells liquid silicon is poured into blocks that are subsequently sawed into plates. This type of approach produces some degree of degradation of the silicon crystals which makes them less efficient.  However, this type of approach is easier and cheaper to manufacture.

Amorphous Thin Film Silicon - This type of solar cell uses layers of semiconductor that are only a few micrometers thick (about 1/100th the thickness of a human hair).  This lower the material cost but makes it even less efficient than the other types of silicon. However, because it is so thin this type of cell has the advantage that it can be placed on a wide variety of flexible materials in order to make things like solar shingles or roof tiles.

Another way of looking at solar cells is in terms of the types of materials they are made with.  While silicon is the most commonly used crystal a number of other materials can be used as well.  These include the following:

gallium arsenide
copper indium diselenide
cadmium telluride

Different types of substances perform better under certain light conditions.  Some cells perform better outdoors (i.e., optimized for sunlight), while others perform better indoors (optimized for fluorescent light).


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